Facile synthesis of SrWO4@MIL-88A(Fe) heterojunctions and their deep treatment of dye wastewater and municipal landfill leachate using photo-Fenton technology
[Display omitted] •SrWO4@MIL-88A(Fe) can double-effectively treat dye wastewater and municipal landfill leachate.•0.33 g/L of SrWO4@MIL-88A(Fe) can degrade 93.75 % of 40 mg/L of MB within 4 min.•0.33 g/L of SrWO4@MIL-88A(Fe) degraded 95 % of MB(40 mg/L) under sunlight + Fenton in 15 min.•Photo-Fento...
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Veröffentlicht in: | Journal of industrial and engineering chemistry (Seoul, Korea) 2023, 120(0), , pp.103-120 |
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Sprache: | eng |
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•SrWO4@MIL-88A(Fe) can double-effectively treat dye wastewater and municipal landfill leachate.•0.33 g/L of SrWO4@MIL-88A(Fe) can degrade 93.75 % of 40 mg/L of MB within 4 min.•0.33 g/L of SrWO4@MIL-88A(Fe) degraded 95 % of MB(40 mg/L) under sunlight + Fenton in 15 min.•Photo-Fenton can eliminate up to 87.19% of COD, 90.23% of BOD5, 99.50% of TOP-P, 80.96% of TOP-N and 81.48% of NH3-N from leachate.
Dye wastewater and municipal landfill leachate greatly threaten the ecological environment and human health. We prepared SrWO4@MIL-88A(Fe) composites in this work by room temperature synthesis. A systematic degradation study of methylene blue (MB) and landfill leachate was carried out using the photo-Fenton process. The results showed that SrWO4@MIL-88A(Fe) could degrade 93.75 % of MB within four min. Within 15 min of sunlight irradiation, SrWO4@MIL-88A(Fe) could degrade up to 95 % of MB. It could eliminate up to 87.19 % of COD, 90.23 % of BOD5, 99.50 % of TOP- P, 80.96 % of TOP-N, and 81.48 % of NH3-N in the leachate. The toxicity of the deep-purified leachate is significantly reduced, and alfalfa seeds can use the remaining organic matter in the leachate to germinate and grow, thus achieving self-purification of the detoxified leachate. In addition, the photo-Fenton technology can effectively kill the bacterial microorganisms in the leachate and reduce the epidemiological hazard to organisms. In conclusion, the photo-Fenton process of SrWO4@MIL-88A(Fe) provides a purification pathway for the dual-effect treatment of MB and municipal landfill leachate. |
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ISSN: | 1226-086X 1876-794X |
DOI: | 10.1016/j.jiec.2022.12.014 |