A new ternary mixed-matrix membrane (PEBAX/PEG/MgO) to enhance CO2/CH4 and CO2/N2 separation efficiency

Mixed-matrix membranes (MMMs) composed of suitable CO 2 -philic polymers and fillers can be attractive candidates for CO 2 /CH 4 and CO 2 /N 2 separation due to their high CO 2 permeability, good thermochemical stability, low fabrication cost, and fast production process. In this research, a novel t...

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Veröffentlicht in:The Korean journal of chemical engineering 2023, 40(6), 279, pp.1457-1473
Hauptverfasser: Azizi, Navid, Jahanmahin, Omid, Homayoon, Reza, Khajouei, Mohammad
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Sprache:eng
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Zusammenfassung:Mixed-matrix membranes (MMMs) composed of suitable CO 2 -philic polymers and fillers can be attractive candidates for CO 2 /CH 4 and CO 2 /N 2 separation due to their high CO 2 permeability, good thermochemical stability, low fabrication cost, and fast production process. In this research, a novel ternary MMM was fabricated via the blending of poly (amide 12- b -ethylene oxide) (PEBAX-1074) with polyethylene glycol (PEG-200) and magnesium oxide (MgO) nanoparticles mixture. The effects of various loadings of the fillers on CO 2 , N 2 , and CH 4 permeability values through the membranes were studied. Permeation of CO 2 , N 2 , and CH 4 gases through the resultant membranes at pressures of 2, 4, 6, 8, and 10 bar and temperatures of 25, 35, 45, and 55 °C revealed the superiority of the MMMs for CO 2 /CH 4 and CO 2 /N 2 separation in comparison with the pristine membranes. Particularly, at 25 °C and 2 bar, the CO 2 permeability, as well as ideal CO 2 /CH 4 and CO 2 /N 2 selectivity of the optimized MMM containing 40 wt% of PEG-200 and 8 wt% of MgO nanoparticles, rose to 210.1 Barrer, 24.9 and 60.9, corresponding to enhancement of around 225%, 23% and 24% of the CO 2 permeability and selectivity compared to the neat membrane, respectively. Thus, the fabricated MMM has a satisfying potential to separate CO 2 from N 2 .
ISSN:0256-1115
1975-7220
DOI:10.1007/s11814-023-1391-5