Ternary charge-transfer complexes. III. Complexes with Group V elements in the anion

Ternary charge-transfer complexes. III. Complexes with Group V elements in the anion

NOMX 6 *aromatic charge-transfer complexes are formed where M may be P, As, orSb, X maybe For Cl, and aromatic may be benzene or a methyl-substituted benzene. Nuclear magnetic resonance and optical spectral parameters are given and three crystal structures reported. Appreciable conductivity is found...

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Veröffentlicht in:Canadian journal of chemistry 1986-08, Vol.64 (8), p.1661-1667
Hauptverfasser: Brownstein, Sydney, Gabe, Eric, Lee, Florence, Piotrowski, Andrej
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Miscellaneous
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Zusammenfassung:NOMX 6 *aromatic charge-transfer complexes are formed where M may be P, As, orSb, X maybe For Cl, and aromatic may be benzene or a methyl-substituted benzene. Nuclear magnetic resonance and optical spectral parameters are given and three crystal structures reported. Appreciable conductivity is found for NOSbCl 6 *polystyrene and NOSbF 6 *hexamethylbenzene.
ISSN:0008-4042
1480-3291
DOI:10.1139/v86-273