Synthèses de dioxolannes α-iodés

Three methods of iodination of cyclic ketals are described. Direct iodination by monoiodine chloride in ether leads to very good yields in monoiodo compounds. A high selectivity is obtained when one of the α-carbon atoms is tertiary.

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Veröffentlicht in:Canadian journal of chemistry 1984-08, Vol.62 (8), p.1548-1551
Hauptverfasser: Daubié, Christophe, Bacquet-Einhorn, Cathy, Lelandais, Daniel
Format: Artikel
Sprache:eng
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Zusammenfassung:Three methods of iodination of cyclic ketals are described. Direct iodination by monoiodine chloride in ether leads to very good yields in monoiodo compounds. A high selectivity is obtained when one of the α-carbon atoms is tertiary.
ISSN:0008-4042
1480-3291
DOI:10.1139/v84-264