Synthèse de pyranno[f et g]indoles

Reaction of ethyl azidoacetate with 6-formylchromans, followed by cyclisation of the azides obtained, leads to 1,7,8,9-tetrahydropyrano[2,3-g]indoles and 2,3,4,8-tetrahydropyrano[3,2-f]indoles. Some aspects of the chemical reactivity of these new tricyclic systems are described. The structures of al...

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Veröffentlicht in:Canadian journal of chemistry 1982-08, Vol.60 (16), p.2093-2098
Hauptverfasser: Kim, Phieo Ta, Guilard, Roger, Renaut, Patrice
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of ethyl azidoacetate with 6-formylchromans, followed by cyclisation of the azides obtained, leads to 1,7,8,9-tetrahydropyrano[2,3-g]indoles and 2,3,4,8-tetrahydropyrano[3,2-f]indoles. Some aspects of the chemical reactivity of these new tricyclic systems are described. The structures of all products synthesized are established on the basis of 1 H nmr data.
ISSN:0008-4042
1480-3291
DOI:10.1139/v82-298