Base-catalyzed Degradations of Carbohydrates. VIII. Disaccharide Syntheses

Base-catalyzed Degradations of Carbohydrates. VIII. Disaccharide Syntheses

Acetylated derivatives ( 3 and 10 ) of the disaccharides 6-O-β- D -glucopyranosyl-3-O-mesyl- D -glucose and 3-deoxy-6-O-β- D -glucopyranosyl- D -ribo-hexose have been synthesized. The parent disaccharides have been degraded to give 2-deoxy-5-O-β- D -glucopyranosyl- D -erythro-pentose ( 4 ) which has...

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Veröffentlicht in:Canadian journal of chemistry 1975-07, Vol.53 (14), p.2178-2181
Hauptverfasser: Aspinall, Gerald O, Krishnamurthy, Thinnayam N, Furda, Ivan
Format: Artikel
Sprache:eng
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Zusammenfassung:Acetylated derivatives ( 3 and 10 ) of the disaccharides 6-O-β- D -glucopyranosyl-3-O-mesyl- D -glucose and 3-deoxy-6-O-β- D -glucopyranosyl- D -ribo-hexose have been synthesized. The parent disaccharides have been degraded to give 2-deoxy-5-O-β- D -glucopyranosyl- D -erythro-pentose ( 4 ) which has been characterized as the methylated disaccharide alditol.
ISSN:0008-4042
1480-3291
DOI:10.1139/v75-303