An Electron Paramagnetic Resonance Study of a fast Lewis Acid-Base Reaction between Copper (II) bis(Diethyldithiocarbamate) and Pyridine in Benzene

An Electron Paramagnetic Resonance Study of a fast Lewis Acid-Base Reaction between Copper (II) bis(Diethyldithiocarbamate) and Pyridine in Benzene

The fast Lewis acid-base reaction between copper(II) bis(diethyldithiocarbamate) and pyridine has been studied from 280 to 320 °K in benzene. The method employed is the analysis of electron paramagnetic resonance line positions and line widths using the solutions of the modified Bloch equations in t...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Canadian journal of chemistry 1972-07, Vol.50 (13), p.2079-2087
Hauptverfasser: Farmer, J. B, Herring, F. G, Tapping, R. L
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The fast Lewis acid-base reaction between copper(II) bis(diethyldithiocarbamate) and pyridine has been studied from 280 to 320 °K in benzene. The method employed is the analysis of electron paramagnetic resonance line positions and line widths using the solutions of the modified Bloch equations in the fast exchange limit. Arrhenius plots, over the temperature range employed, gave values for the thermodynamic data of the process.
ISSN:0008-4042
1480-3291
DOI:10.1139/v72-334