Dimethylsulfoxidepentaammineruthenium(II) Hexafluorophosphate. A Spectroscopic Study
The infrared spectra of [Ru(NH 3 ) 5 (CH 3 ) 2 SO]X 2 , [Ru(ND 3 ) 5 (CH 3 ) 2 SO]X 2 , [Ru(NH 3 ) 5 (CD 3 ) 2 SO]X 2 , and [Ru(ND 3 ) 5 (CD 3 ) 2 SO]X 2 where X = PF 6 − have been examined in detail between 4000-200 cm −1 . These data, together with the 1 H n.m.r. spectrum of [Ru(NH 3 ) 5 (CH 3 ) 2...
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| Veröffentlicht in: | Canadian journal of chemistry 1971-11, Vol.49 (22), p.3585-3589 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The infrared spectra of [Ru(NH
3
)
5
(CH
3
)
2
SO]X
2
, [Ru(ND
3
)
5
(CH
3
)
2
SO]X
2
, [Ru(NH
3
)
5
(CD
3
)
2
SO]X
2
, and [Ru(ND
3
)
5
(CD
3
)
2
SO]X
2
where X = PF
6
−
have been examined in detail between 4000-200 cm
−1
. These data, together with the
1
H n.m.r. spectrum of [Ru(NH
3
)
5
(CH
3
)
2
SO](PF
6
)
2
in D
2
O, suggest that dimethyl sulfoxide is bonded to ruthenium via the sulfur atom in spite of the fact that the ν
so
frequency is not very different from that observed for uncoordinated dimethyl sulfoxide. |
|---|---|
| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v71-599 |