Infrared spectra of triphenylboron and triphenylborate
The infrared spectra of triphenylboron and triphenylborate have been obtained in the region 4000 to300 cm −1 . The analysis of the spectra supports a propeller-shaped structure with symmetry D 3 for triphenylboron and a planar structure with symmetry C 3h for triphenylborate. The Urey-Bradley force...
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| Veröffentlicht in: | Canadian journal of chemistry 1968-06, Vol.46 (12), p.2081-2087 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The infrared spectra of triphenylboron and triphenylborate have been obtained in the region 4000 to300 cm
−1
. The analysis of the spectra supports a propeller-shaped structure with symmetry D
3
for triphenylboron and a planar structure with symmetry C
3h
for triphenylborate. The Urey-Bradley force field has been applied to the calculation of approximate vibrational force constants for the BC
3
and BO
3
groups. |
|---|---|
| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v68-340 |