EFFECT OF α-METHYLATION ON THE PARAMETERS CHARACTERIZING HYDROLYSIS IN WATER FOR A SERIES OF HALIDES AND SULFONATES

EFFECT OF α-METHYLATION ON THE PARAMETERS CHARACTERIZING HYDROLYSIS IN WATER FOR A SERIES OF HALIDES AND SULFONATES

The aim of this work was to explore the effect of α-methylation on the reactivity and detailed mechanism of hydrolysis. Accordingly, rate data and derived parameters are given for the hydrolysis of a series of halides and sulfonates in water. From the differences in kinetic parameters, an attempt is...

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Veröffentlicht in:Canadian journal of chemistry 1966-03, Vol.44 (6), p.677-684
Hauptverfasser: Heppolette, R. L, Robertson, R. E
Format: Artikel
Sprache:eng
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Zusammenfassung:The aim of this work was to explore the effect of α-methylation on the reactivity and detailed mechanism of hydrolysis. Accordingly, rate data and derived parameters are given for the hydrolysis of a series of halides and sulfonates in water. From the differences in kinetic parameters, an attempt is made to infer further information relating structure and mechanism.
ISSN:0008-4042
1480-3291
DOI:10.1139/v66-094