RECENT DEVELOPMENTS IN THE ORGANOMETALLIC CHEMISTRY OF TECHNETIUM. PREPARATION AND PROPERTIES OF A POLYNUCLEAR TETRACARBONYL

RECENT DEVELOPMENTS IN THE ORGANOMETALLIC CHEMISTRY OF TECHNETIUM. PREPARATION AND PROPERTIES OF A POLYNUCLEAR TETRACARBONYL

A polynuclear tetracarbonyl of technetium, constituting a novel class of carbonyls for the manganese subgroup metals, is formed during the treatment of the pentacarbonyl, Tc 2 (CO) 10 , with sodium amalgam and subsequent acidification. The new derivative is characterized, and its possible structure...

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Veröffentlicht in:Canadian Journal of Chemistry (Canada) 1963-05, Vol.41 (5), p.1250-1254
Hauptverfasser: Kaesz, H. D, Huggins, D. K
Format: Artikel
Sprache:eng
Schlagworte:
ACIDITY
CARBONYLS
CHEMICAL REACTIONS
CHEMISTRY
LATTICES
MERCURY ALLOYS
PREPARATION
SODIUM ALLOYS
TECHNETIUM COMPOUNDS
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Beschreibung
Zusammenfassung:A polynuclear tetracarbonyl of technetium, constituting a novel class of carbonyls for the manganese subgroup metals, is formed during the treatment of the pentacarbonyl, Tc 2 (CO) 10 , with sodium amalgam and subsequent acidification. The new derivative is characterized, and its possible structure is discussed.
ISSN:0008-4042
1480-3291
DOI:10.1139/v63-176