Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine

Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine

Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Canadian journal of chemistry 2007-03, Vol.85 (3), p.208-213
Hauptverfasser: Huang, Wen-Ping, Chen, Jia-Rong, Li, Xin-Yong, Cao, Yi-Ju, Xiao, Wen-Jing
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes
Brines
Catalysis
Catalysts
Chemical properties
Chemical reactions
Cyclohexanol
Fructosediphosphate aldolase
Studies
Water
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 213
container_issue 3
container_start_page 208
container_title Canadian journal of chemistry
container_volume 85
creator Huang, Wen-Ping
Chen, Jia-Rong
Li, Xin-Yong
Cao, Yi-Ju
Xiao, Wen-Jing
description Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.
doi_str_mv 10.1139/v07-012
format Article
fullrecord <record><control><sourceid>gale_nrcre</sourceid><recordid>TN_cdi_nrcresearch_primary_10_1139_v07_012</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A163465675</galeid><sourcerecordid>A163465675</sourcerecordid><originalsourceid>FETCH-LOGICAL-c515t-753943ec43b5f18e36b8ff40599ba39f4075d988f0255ab34959a87b3a58cda03</originalsourceid><addsrcrecordid>eNqV0l9rFDEQAPAgFjxb8SssPigKW5PNZjd5PIp_CsVC1Rdfwmx2cpeyl1yTXO1-e1OuiAdVkDwkE36ZmcAQ8pLRU8a4en9L-5qy5glZsFbSmjeKPSULSqmsW9o2z8jzlK5L2NNGLMiPZZo3G8zRmSrEFfhgIMM05xKPLqLJFUxjmKqIYLILPlXBVmY2U1jjXeEeq58ur-8VrucRU-V8NUTn8YQcWZgSvnjYj8n3jx--nX2uLy4_nZ8tL2ojmMh1L7hqOZqWD8IyibwbpLUtFUoNwFU59WJUUtrSr4CBt0ookP3AQUgzAuXH5NU-7zaGmx2mrK_DLvpSUjdMdoJSIQuq92gFE2rnbcgRzAo9RpjKJ6wr10vW8bYTXWnpd9IDb7buRv-JTh9BZY24cebRrG8PHhST8S6vYJeSPv969R_2y6F9s7cmhpQiWr2NbgNx1ozq-6nQZSp0mYoi3-2ljyZiQohm_Q_8-u_4AentaPkvKNXB4w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>218650058</pqid></control><display><type>article</type><title>Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine</title><source>Free Full-Text Journals in Chemistry</source><creator>Huang, Wen-Ping ; Chen, Jia-Rong ; Li, Xin-Yong ; Cao, Yi-Ju ; Xiao, Wen-Jing</creator><creatorcontrib>Huang, Wen-Ping ; Chen, Jia-Rong ; Li, Xin-Yong ; Cao, Yi-Ju ; Xiao, Wen-Jing</creatorcontrib><description>Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v07-012</identifier><identifier>CODEN: CJCHAG</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><subject>Aldehydes ; Brines ; Catalysis ; Catalysts ; Chemical properties ; Chemical reactions ; Cyclohexanol ; Fructosediphosphate aldolase ; Studies ; Water</subject><ispartof>Canadian journal of chemistry, 2007-03, Vol.85 (3), p.208-213</ispartof><rights>COPYRIGHT 2007 NRC Research Press</rights><rights>Copyright National Research Council of Canada Mar 2007</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c515t-753943ec43b5f18e36b8ff40599ba39f4075d988f0255ab34959a87b3a58cda03</citedby><cites>FETCH-LOGICAL-c515t-753943ec43b5f18e36b8ff40599ba39f4075d988f0255ab34959a87b3a58cda03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Huang, Wen-Ping</creatorcontrib><creatorcontrib>Chen, Jia-Rong</creatorcontrib><creatorcontrib>Li, Xin-Yong</creatorcontrib><creatorcontrib>Cao, Yi-Ju</creatorcontrib><creatorcontrib>Xiao, Wen-Jing</creatorcontrib><title>Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.</description><subject>Aldehydes</subject><subject>Brines</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical properties</subject><subject>Chemical reactions</subject><subject>Cyclohexanol</subject><subject>Fructosediphosphate aldolase</subject><subject>Studies</subject><subject>Water</subject><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqV0l9rFDEQAPAgFjxb8SssPigKW5PNZjd5PIp_CsVC1Rdfwmx2cpeyl1yTXO1-e1OuiAdVkDwkE36ZmcAQ8pLRU8a4en9L-5qy5glZsFbSmjeKPSULSqmsW9o2z8jzlK5L2NNGLMiPZZo3G8zRmSrEFfhgIMM05xKPLqLJFUxjmKqIYLILPlXBVmY2U1jjXeEeq58ur-8VrucRU-V8NUTn8YQcWZgSvnjYj8n3jx--nX2uLy4_nZ8tL2ojmMh1L7hqOZqWD8IyibwbpLUtFUoNwFU59WJUUtrSr4CBt0ookP3AQUgzAuXH5NU-7zaGmx2mrK_DLvpSUjdMdoJSIQuq92gFE2rnbcgRzAo9RpjKJ6wr10vW8bYTXWnpd9IDb7buRv-JTh9BZY24cebRrG8PHhST8S6vYJeSPv969R_2y6F9s7cmhpQiWr2NbgNx1ozq-6nQZSp0mYoi3-2ljyZiQohm_Q_8-u_4AentaPkvKNXB4w</recordid><startdate>20070301</startdate><enddate>20070301</enddate><creator>Huang, Wen-Ping</creator><creator>Chen, Jia-Rong</creator><creator>Li, Xin-Yong</creator><creator>Cao, Yi-Ju</creator><creator>Xiao, Wen-Jing</creator><general>NRC Research Press</general><general>Canadian Science Publishing NRC Research Press</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISN</scope><scope>ISR</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FQ</scope><scope>8FV</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2O</scope><scope>M2P</scope><scope>M3G</scope><scope>MBDVC</scope><scope>PADUT</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20070301</creationdate><title>Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine</title><author>Huang, Wen-Ping ; Chen, Jia-Rong ; Li, Xin-Yong ; Cao, Yi-Ju ; Xiao, Wen-Jing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c515t-753943ec43b5f18e36b8ff40599ba39f4075d988f0255ab34959a87b3a58cda03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Aldehydes</topic><topic>Brines</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical properties</topic><topic>Chemical reactions</topic><topic>Cyclohexanol</topic><topic>Fructosediphosphate aldolase</topic><topic>Studies</topic><topic>Water</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Wen-Ping</creatorcontrib><creatorcontrib>Chen, Jia-Rong</creatorcontrib><creatorcontrib>Li, Xin-Yong</creatorcontrib><creatorcontrib>Cao, Yi-Ju</creatorcontrib><creatorcontrib>Xiao, Wen-Jing</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Canada</collection><collection>Gale In Context: Science</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Canadian Business &amp; Current Affairs Database</collection><collection>Canadian Business &amp; Current Affairs Database (Alumni Edition)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric &amp; Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Research Library</collection><collection>Science Database</collection><collection>CBCA Reference &amp; Current Events</collection><collection>Research Library (Corporate)</collection><collection>Research Library China</collection><collection>Earth, Atmospheric &amp; Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Wen-Ping</au><au>Chen, Jia-Rong</au><au>Li, Xin-Yong</au><au>Cao, Yi-Ju</au><au>Xiao, Wen-Jing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>2007-03-01</date><risdate>2007</risdate><volume>85</volume><issue>3</issue><spage>208</spage><epage>213</epage><pages>208-213</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><coden>CJCHAG</coden><abstract>Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v07-012</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0008-4042
ispartof Canadian journal of chemistry, 2007-03, Vol.85 (3), p.208-213
issn 0008-4042
1480-3291
language eng
recordid cdi_nrcresearch_primary_10_1139_v07_012
source Free Full-Text Journals in Chemistry
subjects Aldehydes
Brines
Catalysis
Catalysts
Chemical properties
Chemical reactions
Cyclohexanol
Fructosediphosphate aldolase
Studies
Water
title Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T11%3A50%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_nrcre&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Asymmetric%20organocatalytic%20direct%20aldol%20reactions%20of%20cyclohexanone%20with%20aldehydes%20in%20brine&rft.jtitle=Canadian%20journal%20of%20chemistry&rft.au=Huang,%20Wen-Ping&rft.date=2007-03-01&rft.volume=85&rft.issue=3&rft.spage=208&rft.epage=213&rft.pages=208-213&rft.issn=0008-4042&rft.eissn=1480-3291&rft.coden=CJCHAG&rft_id=info:doi/10.1139/v07-012&rft_dat=%3Cgale_nrcre%3EA163465675%3C/gale_nrcre%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=218650058&rft_id=info:pmid/&rft_galeid=A163465675&rfr_iscdi=true