Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine

Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.

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Bibliographische Detailangaben
Veröffentlicht in:	Canadian journal of chemistry 2007-03, Vol.85 (3), p.208-213
Hauptverfasser:	Huang, Wen-Ping, Chen, Jia-Rong, Li, Xin-Yong, Cao, Yi-Ju, Xiao, Wen-Jing
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Brines Catalysis Catalysts Chemical properties Chemical reactions Cyclohexanol Fructosediphosphate aldolase Studies Water
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Beschreibung
Zusammenfassung:	Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.
ISSN:	0008-4042 1480-3291
DOI:	10.1139/v07-012