A metal-free catalytic intramolecular hydrosilylation
A metal-free catalytic intramolecular hydrosilylation reaction is reported. The key intermediates in the catalytic cycle are silyl cationic species. The reaction is used to produce 2-silanorbornanes 2 from 3-cyclopentenemethylsilanes 1 under mild conditions and in high isolated yields.Key words: hyd...
Gespeichert in:
| Veröffentlicht in: | Canadian journal of chemistry 2003-11, Vol.81 (11), p.1223-1227 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | A metal-free catalytic intramolecular hydrosilylation reaction is reported. The key intermediates in the catalytic cycle are silyl cationic species. The reaction is used to produce 2-silanorbornanes
2
from 3-cyclopentenemethylsilanes
1
under mild conditions and in high isolated yields.Key words: hydrosilylation, catalysis, silaheterocycles, silyl cations. |
|---|---|
| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v03-121 |