Synthesis of ω-Ferrocenylpentyltrichlorosilane and Its Conductive Cast Films

Synthesis of ω-Ferrocenylpentyltrichlorosilane and Its Conductive Cast Films

A novel trichlorosilane (1) having a ω-ferrocenylpentyl chain has been synthesized by hydrosilylation of the corresponding olefin using hydrogen hexachloroplatinate catalyst under mild conditions (room temperature, 4 h). Cast films of 1 on glasses had high surface resistivities ＞ 1 × 1013 Ωsq-1, whe...

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Veröffentlicht in:Journal of Oleo Science 2003, Vol.52 (9), p.505-508
Hauptverfasser: Yukishige KONDO, Kentaro MlYAZAWA, Yoichi KUNUGI, Yasuhiro TAKAHASHI, Haruhiko MIYAZAWA, Kensuke MIYAO, Tatsuya TSUKAGOSHI, Norio YOSHINO
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Sprache:jpn
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Zusammenfassung:A novel trichlorosilane (1) having a ω-ferrocenylpentyl chain has been synthesized by hydrosilylation of the corresponding olefin using hydrogen hexachloroplatinate catalyst under mild conditions (room temperature, 4 h). Cast films of 1 on glasses had high surface resistivities ＞ 1 × 1013 Ωsq-1, whereas I2-doping made the films more conductive. It was found that the resistivity decreases with increasing surface concentration of 1, namely film thickness.
ISSN:1345-8957