Photo-Induced Aziridination of Alkenes with N-Sulfonyliminoiodinanes

Photo-Induced Aziridination of Alkenes with N-Sulfonyliminoiodinanes

Activation of N-sulfonyliminiodinanes was achieved by photo-irradiation at 375nm, which enabled the reaction with several alkenes to afford the corresponding aziridines. Mechanistic studies suggested that the reaction would proceed through a stepwise mechanism via radical intermediates rather than t...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical and Pharmaceutical Bulletin 2018-06, Vol.66 (6), p.688-690
Hauptverfasser: Sota Masakado, Yusuke Kobayashi, Yoshiji Takemoto
Format: Artikel
Sprache:jpn
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Activation of N-sulfonyliminiodinanes was achieved by photo-irradiation at 375nm, which enabled the reaction with several alkenes to afford the corresponding aziridines. Mechanistic studies suggested that the reaction would proceed through a stepwise mechanism via radical intermediates rather than through a concerted process.
ISSN:0009-2363