Microbial Metabolism. Part 5. 1) Dihydrokawain

Microbial Metabolism. Part 5. 1) Dihydrokawain

Preparative scale fermentation of (6S)-dihydrokawain (1) with Rhizopus arrhizus (ATCC 11145) gave 3'-hydroxydihydrokawain (2) and (8S)-hydroxydihydrokawain (3). Structure elucidation of the metabolites was based on spectroscopic data. The C-8 absolute configuration of (3) was assessed via its M...

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Veröffentlicht in:Chemical & Pharmaceutical Bulletin 2004, Vol.52 (11), p.1372-1374
Hauptverfasser: Wimal HERATHa, Daneel FERREIRAa, b, Julie Rakel MIKELLa, Ikhlas Ahmad KHANa
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Sprache:jpn
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Zusammenfassung:Preparative scale fermentation of (6S)-dihydrokawain (1) with Rhizopus arrhizus (ATCC 11145) gave 3'-hydroxydihydrokawain (2) and (8S)-hydroxydihydrokawain (3). Structure elucidation of the metabolites was based on spectroscopic data. The C-8 absolute configuration of (3) was assessed via its Mosher's esters.
ISSN:0009-2363