Preparation of ultrasmall cyclodextrin nanogels by an inverse emulsion method using a cationic surfactant

Stable water-in-oil emulsion membranes can be prepared using [dilauryl(dimethyl)ammonium] bromide (DDAB), a cationic surfactant. We prepared ultrasmall cyclodextrin (γ-CyD) nanogels (γ-CyDngs) by forming ionic pairs between the secondary hydroxyl groups of γ-CyDs and DDAB. Fluorescence and NMR chara...

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Veröffentlicht in:CHEMICAL COMMUNICATIONS 2023-03, Vol.59 (27), p.4071-4074
Hauptverfasser: Takeuchi, Satomi, Cesari, Andrea, Soma, Suzuka, Suzuki, Yota, Casulli, Maria Antonietta, Sato, Kai, Mancin, Fabrizio, Hashimoto, Takeshi, Hayashita, Takashi
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Sprache:eng
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Zusammenfassung:Stable water-in-oil emulsion membranes can be prepared using [dilauryl(dimethyl)ammonium] bromide (DDAB), a cationic surfactant. We prepared ultrasmall cyclodextrin (γ-CyD) nanogels (γ-CyDngs) by forming ionic pairs between the secondary hydroxyl groups of γ-CyDs and DDAB. Fluorescence and NMR characterisation of the obtained γ-CyDngs revealed superior inclusion affinities compared with native γ-CyDs, beneficial for the solubilisation of hydrophobic compounds in water.
ISSN:1359-7345