Chemical Vapor Deposition and High-Resolution Patterning of a Highly Conductive Two-Dimensional Coordination Polymer Film
Crystalline coordination polymers with high electrical conductivities and charge carrier mobilities might open new opportunities for electronic devices. However, current solvent-based synthesis methods hinder compatibility with microfabrication standards. Here, we describe a solvent-free chemical va...
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Veröffentlicht in: | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 2023-01, Vol.145 (1), p.152-159 |
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creator | Rubio-Gimenez, Victor Arnauts, Giel Wang, Mingchao Mata, Eduardo Sergio Oliveros Huang, Xing Lan, Tianshu Tietze, Max L Kravchenko, Dmitry E Smets, Jorid Wauteraerts, Nathalie Khadiev, Azat Novikov, Dmitri Makarov, Denys Dong, Renhao Ameloot, Rob |
description | Crystalline coordination polymers with high electrical conductivities and charge carrier mobilities might open new opportunities for electronic devices. However, current solvent-based synthesis methods hinder compatibility with microfabrication standards. Here, we describe a solvent-free chemical vapor deposition method to prepare high-quality films of the two-dimensional conjugated coordination polymer Cu-BHT (BHT = benzenehexanothiolate). This approach involves the conversion of a metal oxide precursor into Cu-BHT nanofilms with a controllable thickness (20-85 nm) and low roughness ( |
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title | Chemical Vapor Deposition and High-Resolution Patterning of a Highly Conductive Two-Dimensional Coordination Polymer Film |
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