Calix[n]triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on" fluorescen...

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Veröffentlicht in:CHEMICAL COMMUNICATIONS 2021-11, Vol.57 (91), p.12139-12142
Hauptverfasser: Cho, Jihee, Shin, Jinwoo, Kang, Minjung, Verwilst, Peter, Lim, Changhyun, Yoo, Hanbin, Kim, Jeung Gon, Zhang, Xingcai, Hong, Chang Seop, Kim, Jong Seung, Kim, Sanghee
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container_end_page 12142
container_issue 91
container_start_page 12139
container_title CHEMICAL COMMUNICATIONS
container_volume 57
creator Cho, Jihee
Shin, Jinwoo
Kang, Minjung
Verwilst, Peter
Lim, Changhyun
Yoo, Hanbin
Kim, Jeung Gon
Zhang, Xingcai
Hong, Chang Seop
Kim, Jong Seung
Kim, Sanghee
description A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on" fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.
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title Calix[n]triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection
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