Calix[n]triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

Calix[n]triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on" fluorescen...

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Veröffentlicht in:CHEMICAL COMMUNICATIONS 2021-11, Vol.57 (91), p.12139-12142
Hauptverfasser: Cho, Jihee, Shin, Jinwoo, Kang, Minjung, Verwilst, Peter, Lim, Changhyun, Yoo, Hanbin, Kim, Jeung Gon, Zhang, Xingcai, Hong, Chang Seop, Kim, Jong Seung, Kim, Sanghee
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Sprache:eng
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Zusammenfassung:A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on" fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.
ISSN:1359-7345