The specific heat of β- brass
The specific heat of β-brass as measured by Sykes (1935) and by Moser (1936) shows an anomalous rise beginning at 160° C a sharp maximum- a λ-point-is reached and the specific heat drops abruptly to low values, the whole drop taking place with in 7°. Moser states that this drop is steep but continuo...
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Veröffentlicht in: | Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences Mathematical and physical sciences, 1938-11, Vol.168 (935), p.546-566 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The specific heat of β-brass as measured by Sykes (1935) and by Moser (1936) shows an anomalous rise beginning at 160° C a sharp maximum- a λ-point-is reached and the specific heat drops abruptly to low values, the whole drop taking place with in 7°. Moser states that this drop is steep but continuous. Both authors obtain a slope of 0·03 cal./degree2g. approximately by interpolating between their experimental values. The thermal expansion coefficient goes parallel with the specific heat and has a maximum of similar shape (Steinwehr and Schulze 1934). This phenomenon is explained as the transition of the Cu and Zn atoms from an ordered arrangement to disorder. |
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ISSN: | 0080-4630 2053-9169 |
DOI: | 10.1098/rspa.1938.0190 |