Catalytic Asymmetric Synthesis of All-Carbon Quaternary Stereocenters

Only a few catalytic asymmetric C-C bond-forming reactions have been shown to be useful for constructing all-carbon quaternary stereocenters. This Perspective examines the current state of such methods.

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Bibliographische Detailangaben
Veröffentlicht in:	Proceedings of the National Academy of Sciences - PNAS 2004-04, Vol.101 (15), p.5363-5367
Hauptverfasser:	Douglas, Christopher J., Overman, Larry E.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Carbon Catalysis Catalysts Diels Alder reactions Dienes Ketones Ligands Nucleophiles Organic chemistry Overman Perspectives
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Only a few catalytic asymmetric C-C bond-forming reactions have been shown to be useful for constructing all-carbon quaternary stereocenters. This Perspective examines the current state of such methods.
ISSN:	0027-8424 1091-6490
DOI:	10.1073/pnas.0307113101