Iron Chemistry of a Pentadentate Ligand That Generates a Metastable FeIII−OOH Intermediate

In an effort to gain more insight into the factors controlling the formation of low-spin non-heme FeIII−peroxo intermediates in oxidation catalysis, such as activated bleomycin, we have synthesized a series of iron complexes based on the pentadentate ligand N4Py (N4Py = N,N-bis(2-pyridylmethyl)-N-(b...

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Veröffentlicht in:	Inorganic chemistry 1999-04, Vol.38 (8), p.1929-1936
Hauptverfasser:	Roelfes, Gerard, Lubben, Marcel, Chen, Kui, Ho, Raymond Y. N, Meetsma, Auke, Genseberger, Susan, Hermant, Roel M, Hage, Ronald, Mandal, Sanjay K, Young, Victor G, Zang, Yan, Kooijman, Huub, Spek, Anthony L, Que, Lawrence, Feringa, Ben L
Format:	Artikel
Sprache:	eng
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