A Cube in a Tetrahedron:  Microwave-Assisted Synthesis of an Octametallic FeIII Cluster

A Cube in a Tetrahedron:  Microwave-Assisted Synthesis of an Octametallic FeIII Cluster

The microwave-assisted reaction of Fe(O2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.

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Veröffentlicht in:Inorganic chemistry 2006-07, Vol.45 (14), p.5281-5283
Hauptverfasser: Gass, Ian A, Milios, Constantinos J, Whittaker, A. Gavin, Fabiani, Francesca P. A, Parsons, Simon, Murrie, Mark, Perlepes, Spyros P, Brechin, Euan K
Format: Artikel
Sprache:eng
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Zusammenfassung:The microwave-assisted reaction of Fe(O2CMe)2 with salicylaldoxime (saoH2) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao2- exhibits a novel coordination mode.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic0607843