Formation of C76F38, C78F38, C82F44, C84F40, and C84F44

Formation of C76F38, C78F38, C82F44, C84F40, and C84F44

The main products from fluorination of [76−84]fullerenes with inorganic fluorides at ca. 500 °C are C76F38, C78F38, C82F44, C84F40 (two isomers), and C84F44, which have been separated by HPLC; the formation of C84F40 and the known high stability of C84H40 indicate a common underlying cause.

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Veröffentlicht in:The journal of physical chemistry. B 1999-09, Vol.103 (38), p.8189-8191
Hauptverfasser: Boltalina, Olga V, Avakyan, Tigran V, Markov, Vitaliy Y, Dennis, T. John S, Abdul-Sada, Ala'a K, Taylor, Roger
Format: Artikel
Sprache:eng
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Zusammenfassung:The main products from fluorination of [76−84]fullerenes with inorganic fluorides at ca. 500 °C are C76F38, C78F38, C82F44, C84F40 (two isomers), and C84F44, which have been separated by HPLC; the formation of C84F40 and the known high stability of C84H40 indicate a common underlying cause.
ISSN:1520-6106
1520-5207
DOI:10.1021/jp992504t