Coordination of C60 to Penta- and Hexaruthenium Cluster Frames

Coordination of C60 to Penta- and Hexaruthenium Cluster Frames

In refluxing chlorobenzene C60 reacts with Ru5C(CO)15 or with Ru6C(CO)17 to form new complexes, which are isolated following treatment with tertiary phosphines to give the structurally characterized, face-bonded derivatives Ru5C(CO)11(PPh3)(μ3-η2:η2:η2-C60) (1) and Ru6C(CO)12(dppm)(μ3-η2:η2:η2-C60)...

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Veröffentlicht in:Organometallics 1997-09, Vol.16 (18), p.3876-3877
Hauptverfasser: Lee, Kwangyeol, Hsu, Hsiu-Fu, Shapley, John R
Format: Artikel
Sprache:eng
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Zusammenfassung:In refluxing chlorobenzene C60 reacts with Ru5C(CO)15 or with Ru6C(CO)17 to form new complexes, which are isolated following treatment with tertiary phosphines to give the structurally characterized, face-bonded derivatives Ru5C(CO)11(PPh3)(μ3-η2:η2:η2-C60) (1) and Ru6C(CO)12(dppm)(μ3-η2:η2:η2-C60) (2).
ISSN:0276-7333
1520-6041
DOI:10.1021/om970265v