Asymmetric Fluoro-alkynyl Mercurials:  The Synthesis and Solid State Structures of RHgC⋮CCF3 (R = Ph, Fc)

Asymmetric Fluoro-alkynyl Mercurials:  The Synthesis and Solid State Structures of RHgC⋮CCF3 (R = Ph, Fc)

The fluoro-alkynyl mercurials RHgC⋮CCF3 (R = Ph, Fc) have been prepared, from the respective organomercurihalides and LiC⋮CCF3, and are the first examples of such materials to be studied crystallographically. These studies have revealed the presence of appreciable mercury-centered intermolecular int...

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Veröffentlicht in:Organometallics 2005-10, Vol.24 (22), p.5487-5490
Hauptverfasser: Brisdon, Alan K, Crossley, Ian R, Pritchard, Robin G
Format: Artikel
Sprache:eng
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Zusammenfassung:The fluoro-alkynyl mercurials RHgC⋮CCF3 (R = Ph, Fc) have been prepared, from the respective organomercurihalides and LiC⋮CCF3, and are the first examples of such materials to be studied crystallographically. These studies have revealed the presence of appreciable mercury-centered intermolecular interactions in the extended structures, including an apparent mercurophilic interaction.
ISSN:0276-7333
1520-6041
DOI:10.1021/om050366q