Evidence for the Pathway of Metal Triangle Rotation in Solid M3(CO)12: Variable-Temperature X-ray Structures of Fe2Ru(CO)12 and FeRu2(CO)12

Fe2Ru(CO)12 has the Fe3(CO)12 structure, while FeRu2(CO)12 has an all-terminal D 3 structure: the metal disorder in FeRu2(CO)12 at high temperatures provides direct evidence for the pathway of metal triangle rotation in the solid state.

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Bibliographische Detailangaben
Veröffentlicht in:	Organometallics 1996-10, Vol.15 (22), p.4684-4686
Hauptverfasser:	Braga, Dario, Farrugia, Louis J, Gillon, Amy L, Grepioni, Fabrizia, Tedesco, Emilio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Fe2Ru(CO)12 has the Fe3(CO)12 structure, while FeRu2(CO)12 has an all-terminal D 3 structure: the metal disorder in FeRu2(CO)12 at high temperatures provides direct evidence for the pathway of metal triangle rotation in the solid state.
ISSN:	0276-7333 1520-6041
DOI:	10.1021/om960512f