Preparation, Crystal Structure Analysis, and Catalytic Application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2

Preparation, Crystal Structure Analysis, and Catalytic Application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2

The efficient preparation of [(S)-BINAP]Ni(COD) (1) and [(S)-BINAP]NiBr2 (2) is reported. X-ray crystal structure analysis of these potential precatalysts provides the first structural insights into the nickel−BINAP system at both the 0 and +2 oxidation states.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 2002-09, Vol.21 (18), p.3833-3836
Hauptverfasser: Spielvogel, Dirk J, Davis, William M, Buchwald, Stephen L
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The efficient preparation of [(S)-BINAP]Ni(COD) (1) and [(S)-BINAP]NiBr2 (2) is reported. X-ray crystal structure analysis of these potential precatalysts provides the first structural insights into the nickel−BINAP system at both the 0 and +2 oxidation states.
ISSN:0276-7333
1520-6041
DOI:10.1021/om020164j