Asymmetric conjugate addition

A study examines synthetic methods developed for diastereoselective conjugate addition (DCA) to scalemic substances giving diastereomerically enriched products that are subsequently transformed to enantiomers. Chiral reagents developed to react enantioselectively with prochiral substrates are also i...

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Veröffentlicht in:	Chemical reviews 1992-07, Vol.92 (5), p.771-806
Hauptverfasser:	Rossiter, Bryant E, Swingle, Nicole M
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A study examines synthetic methods developed for diastereoselective conjugate addition (DCA) to scalemic substances giving diastereomerically enriched products that are subsequently transformed to enantiomers. Chiral reagents developed to react enantioselectively with prochiral substrates are also investigated.
ISSN:	0009-2665 1520-6890
DOI:	10.1021/cr00013a002