Structural Determination of the La@C82 Isomer
A stable diamagnetic monoanion of the La@C82 isomer was electrochemically prepared and isolated in order to disclose its cage symmetry. By measuring the 13C NMR spectrum of the anion, it was determined for the first time that the isomer has C s symmetry, as was also confirmed by density functional c...
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| Veröffentlicht in: | The journal of physical chemistry. B 2001-04, Vol.105 (15), p.2971-2974 |
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| container_end_page | 2974 |
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| container_issue | 15 |
| container_start_page | 2971 |
| container_title | The journal of physical chemistry. B |
| container_volume | 105 |
| creator | Akasaka, Takeshi Wakahara, Takatsugu Nagase, Shigeru Kobayashi, Kaoru Waelchli, Markus Yamamoto, Kazunori Kondo, Masahiro Shirakura, Shingo Maeda, Yutaka Kato, Tatsuhisa Kako, Masahiro Nakadaira, Yasuhiro Gao, Xiang Van Caemelbecke, Eric Kadish, Karl M |
| description | A stable diamagnetic monoanion of the La@C82 isomer was electrochemically prepared and isolated in order to disclose its cage symmetry. By measuring the 13C NMR spectrum of the anion, it was determined for the first time that the isomer has C s symmetry, as was also confirmed by density functional calculations. |
| doi_str_mv | 10.1021/jp003930d |
| format | Article |
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| identifier | ISSN: 1520-6106 |
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| language | eng |
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| source | ACS Publications |
| title | Structural Determination of the La@C82 Isomer |
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