Structural Determination of the La@C82 Isomer

Structural Determination of the La@C82 Isomer

A stable diamagnetic monoanion of the La@C82 isomer was electrochemically prepared and isolated in order to disclose its cage symmetry. By measuring the 13C NMR spectrum of the anion, it was determined for the first time that the isomer has C s symmetry, as was also confirmed by density functional c...

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Veröffentlicht in:The journal of physical chemistry. B 2001-04, Vol.105 (15), p.2971-2974
Hauptverfasser: Akasaka, Takeshi, Wakahara, Takatsugu, Nagase, Shigeru, Kobayashi, Kaoru, Waelchli, Markus, Yamamoto, Kazunori, Kondo, Masahiro, Shirakura, Shingo, Maeda, Yutaka, Kato, Tatsuhisa, Kako, Masahiro, Nakadaira, Yasuhiro, Gao, Xiang, Van Caemelbecke, Eric, Kadish, Karl M
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Sprache:eng
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Zusammenfassung:A stable diamagnetic monoanion of the La@C82 isomer was electrochemically prepared and isolated in order to disclose its cage symmetry. By measuring the 13C NMR spectrum of the anion, it was determined for the first time that the isomer has C s symmetry, as was also confirmed by density functional calculations.
ISSN:1520-6106
1520-5207
DOI:10.1021/jp003930d