Hydrolytic Reactivity of a Samarium(II) Organometallic Complex:  Synthesis and Structure of a Hexametallic Organosamarium Oxide Hydroxide, [(C5Me5)Sm]6O9H6

Hydrolytic Reactivity of a Samarium(II) Organometallic Complex:  Synthesis and Structure of a Hexametallic Organosamarium Oxide Hydroxide, [(C5Me5)Sm]6O9H6

Controlled hydrolysis of the divalent organosamarium complex (C5Me5)2Sm(THF)2 in THF forms [(C5Me5)Sm]6O9H6, 1, which has a solid-state structure consisting of a distorted octahedral array of six [(C5Me5)Sm]2+ units connected by eight triply bridging oxygens and a central oxygen.

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Veröffentlicht in:Organometallics 2001-06, Vol.20 (13), p.2936-2937
Hauptverfasser: Evans, William J, Allen, Nathan T, Greci, Michael A, Ziller, Joseph W
Format: Artikel
Sprache:eng
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Zusammenfassung:Controlled hydrolysis of the divalent organosamarium complex (C5Me5)2Sm(THF)2 in THF forms [(C5Me5)Sm]6O9H6, 1, which has a solid-state structure consisting of a distorted octahedral array of six [(C5Me5)Sm]2+ units connected by eight triply bridging oxygens and a central oxygen.
ISSN:0276-7333
1520-6041
DOI:10.1021/om010171s