Product Branching Ratios of the NH2(X2B1) + NO2 Reaction
The reaction of NH2(X2B1) with NO2 was studied at 298 K using time-resolved infrared diode laser spectroscopy to detect N2O and NO products. The N2O + H2O channel was confirmed to be a rather minor contribution to the overall reaction, with a branching ratio of 0.24 ± 0.04. The branching ratio of th...
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| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1997-07, Vol.101 (27), p.4991-4995 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction of NH2(X2B1) with NO2 was studied at 298 K using time-resolved infrared diode laser spectroscopy to detect N2O and NO products. The N2O + H2O channel was confirmed to be a rather minor contribution to the overall reaction, with a branching ratio of 0.24 ± 0.04. The branching ratio of the NO + H2NO channel was measured to be 0.76 ± 0.1. |
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| ISSN: | 1089-5639 1520-5215 |
| DOI: | 10.1021/jp970994o |