Rheological properties of mono- and polydomain liquidcrystalline elastomers exhibiting a broad smectic A phase

We investigate the rheological properties of polydomain smectic A Side-Chain Liquid Crystalline Elastomers (SCLCE) by dynamic shear and compression measurements and find a very similar behavior for both experiments. We show that the dynamic shear modulus G' is independent of a precompression ap...

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Veröffentlicht in:Europhysics letters 1999-08, Vol.47 (4), p.508-514
Hauptverfasser: Weilepp, J., Stein, P., Aßfalg, N., Finkelmann, H., Martinoty, P., Brand, H. R.
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Sprache:eng
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Zusammenfassung:We investigate the rheological properties of polydomain smectic A Side-Chain Liquid Crystalline Elastomers (SCLCE) by dynamic shear and compression measurements and find a very similar behavior for both experiments. We show that the dynamic shear modulus G' is independent of a precompression applied to the sample. In addition, we present the first dynamic measurements of the anisotropy of G' observed for the corresponding Liquid Single Crystal Elastomers (LSCE). We find that these monodomains show dynamically a dramatic difference depending on whether the shear is in a plane parallel or perpendicular to the layer normal, demonstrating the in-plane fluidity of the smectic layering.
ISSN:0295-5075
1286-4854
DOI:10.1209/epl/i1999-00417-3