The van der Waals potential between metastable atoms and solid surfaces: Novel diffraction experiments vs. theory

Highly polarizable metastable $\chem{He^*}$ $(2^3S)$ and $\chem{Ne^*}$ $(2^3P)$ atoms have been diffracted from a 100$\un{nm}$ period silicon nitride transmission grating and the van der Waals coefficients C3 for the interaction of the excited atoms with the silicon nitride surface have been determined from the diffraction intensities out to the 10th order. The results agree with calculations based on the non-retarded Lifshitz formula.