A model for the generic alpha relaxation of viscous liquids

Dielectric measurements on molecular liquids just above the glass transition indicate that alpha relaxation is characterized by a generic high-frequency loss varying as $\omega^{-1/2}$, whereas deviations from this come from one or more low-lying beta processes (Olsen et al. , Phys. Rev. Lett. 86 (2...

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Veröffentlicht in:Europhysics letters 2005-08, Vol.71 (4), p.646-650
1. Verfasser: Dyre, J. C
Format: Artikel
Sprache:eng
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Zusammenfassung:Dielectric measurements on molecular liquids just above the glass transition indicate that alpha relaxation is characterized by a generic high-frequency loss varying as $\omega^{-1/2}$, whereas deviations from this come from one or more low-lying beta processes (Olsen et al. , Phys. Rev. Lett. 86 (2001) 1271). Assuming that long-wavelength fluctuations dominate the dynamics, a model for the dielectric alpha relaxation based on the simplest coupling between the density and dipole density fields is proposed here. The model, which is solved in second-order perturbation theory in the Gaussian approximation, reproduces the generic features of alpha relaxation.
ISSN:0295-5075
1286-4854
DOI:10.1209/epl/i2005-10122-3