Effects of action at a distance in water

Dipole-dipole interaction between molecules of hydrogen-bonding polar liquids (HBPLs), which has a collective and long-range nature, determines the basic large-scale properties of such liquids. We present a two-scale phenomenological vector model of polar liquids (VMPLs), wherein the liquid is descr...

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Veröffentlicht in:Physics Uspekhi 2020-08, Vol.63 (5), p.440-486
Hauptverfasser: Menshikov, L I, Menshikov, P L, Fedichev, P O
Format: Artikel
Sprache:eng
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Zusammenfassung:Dipole-dipole interaction between molecules of hydrogen-bonding polar liquids (HBPLs), which has a collective and long-range nature, determines the basic large-scale properties of such liquids. We present a two-scale phenomenological vector model of polar liquids (VMPLs), wherein the liquid is described by a polarization vector. The simplest version of this model satisfactorily reproduces the well-known properties of HBPLs and interaction between macroscopic objects in a liquid. The possible existence of a ferroelectric phase transition (FPT) in supercooled liquid water is discussed. Near the FPT, fluctuations of the polarization vector increase, which may be the cause of the so-called 'anomalous' properties of water. We propose a quantitative classification of body surfaces based on the properties of their wettability by polar liquids. The ordering of dipoles of molecules located in the near-surface layers of HBPLs and phase transitions in these layers are discussed. The proposed model enables a significant reduction in computer time in numerical simulations of systems that contain a large number of water molecules.
ISSN:1063-7869
1468-4780
DOI:10.3367/UFNe.2020.01.038721