Influence of Sidechain Length in Perfluoro-Sulfonic Acid Ionomer on Electrode Slurry Interactions and Finalized Microstructure in the Polymer Electrolyte Fuel Cells

Polymer electrolyte fuel cells (PEFCs) have emerged as one of the most promising next-generation energy devices for both passenger-owned and heavy-duty vehicles due to their high energy efficiency, low emissions, and quiet operation. However, the performance of the fuel cell electrode is often limited by the strong specific adsorption of long sidechain (LSC) perfluoro-sulfonic acid (PFSA) ionomer onto the platinum (Pt) catalyst 2 , which results in a decrease in the electrocatalytic activity 1 as well as increase oxygen mass transport resistenace at the MEA level. To address this issue, a short sidechain (SSC) ionomer has been developed, which has been found to exhibit excellent efficiency over LSC ionomer 3 The reduced specific adsorption of SSC ionomer onto the Pt catalyst results in a higher available surface area for the electrochemical reaction, which improves the overall fuel cell performance. The sidechain length of ionomers plays a crucial role in determining the overall cell performance 4 however, due to the differences between them, the interactions among slurry components are not yet fully understood. Unlike the previous literatures, we investigates the details of ionomer sidechain length and its impact on the interaction among slurry components and resulting electrode microstructure, through a comparative analysis of LSC and SSC ionomers. 5 Our hypothesis propose that the physical interactions between components are considerably impacted by the sidechains with a specific emphasis on the mobility and ion-pair association in the slurry. To probe the influence of ionomer sidechains, we conducted a thorough investigation wherein incrementally varied its concentration from 0 to 1.5 mmol SO3- g C -1 , at intervals of 0.3 mmol SO3- g C -1 . The main purpose of this evaluation was to observe the evolution of particle aggregation according to the correlation between adsorbed ionomer and free ionomer in electrode slurry. Drawing from the U-shaped viscosity profile obtained through rheological measurements, we propose an optimized ionomer concentration of 0.6 mmol SO3- g C -1 for the SSC ionomer-based slurry and 0.9 mmol SO3- g C -1 for the LSC ionomer-based slurry. To characterize the microstructure of the as-prepared electrode, we employed scanning electron microscopy (SEM) and confocal microscopy, with a focus on particle agglomeration and the homogeneous ionomer distribution. Finally, the electrochemical analysis was performed on the fabricated membra