Development and Study of Self-Sustained Electrochemical Promotion Catalysts for Hydrocarbon Reforming

A series of study on self-sustained electrochemical promotion (SSEP) catalysts are summarized. The SSEP catalyst enables more than 90% conversion and 90% hydrogen sensitivity at temperatures of 450 - 650 ºC for methane and n-pentadecane reforming. The conversion and sensitivity is up to two orders o...

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Veröffentlicht in:ECS transactions 2013-01, Vol.58 (2), p.243-254
Hauptverfasser: Huang, Hao, Wang, Zedong, Zhou, Xiangyang, Liu, Hongtan, Wei, Yongsheng, Pramuanjaroenkij, Anchasa, Bordas, Alexi, Page, Michael, Cai, Sirui, Zhang, Xuyang
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Sprache:eng
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Zusammenfassung:A series of study on self-sustained electrochemical promotion (SSEP) catalysts are summarized. The SSEP catalyst enables more than 90% conversion and 90% hydrogen sensitivity at temperatures of 450 - 650 ºC for methane and n-pentadecane reforming. The conversion and sensitivity is up to two orders of magnitude greater than those over Ni based catalyst and a commercial Pt catalyst at 450-550°C. The kinetic models incorporating Langmuir-Hinshelwood model and SSEP effect successfully describe the major characteristics of hydrocarbons reforming over the SSEP catalyst. This concept of SSEP catalyst may provide a new route for developing high performance catalysts for hydrocarbons reforming.
ISSN:1938-5862
1938-6737
DOI:10.1149/05802.0243ecst