Tetrabenzotriazaporphyrins: synthesis, properties and application

Synthetic approaches to tetrabenzotriazaporphyrins and their complexes with metals and semimetals (P, Si) are considered. Methods for complexation of free-base tetrabenzotriazaporphyrin ligands and the preparation of water-soluble derivatives via the introduction of a sulfo group are analyzed. Parti...

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Veröffentlicht in:Russian chemical reviews 2014-01, Vol.83 (7), p.657-675
Hauptverfasser: Kalashnikov, V V, Pushkarev, V E, Tomilova, L G
Format: Artikel
Sprache:eng
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Zusammenfassung:Synthetic approaches to tetrabenzotriazaporphyrins and their complexes with metals and semimetals (P, Si) are considered. Methods for complexation of free-base tetrabenzotriazaporphyrin ligands and the preparation of water-soluble derivatives via the introduction of a sulfo group are analyzed. Particular attention is given to investigations of this class of compounds by electronic absorption spectroscopy and possibilities of their practical application. The bibliography includes 80 references.
ISSN:0036-021X
1468-4837
DOI:10.1070/RC2014v083n07ABEH004421