Interaction of Donors with Electron Deficient Low-Coordinated Phosphorus Compounds

Interaction of Donors with Electron Deficient Low-Coordinated Phosphorus Compounds

Mono-and bis-donor-acceptor formation (donor=AH 3 , Y = N, P, As, Sb, Bi and AH 2 , O, S, Se, Te) is discussed on the basis of quantum chemical (ab initio) calculations for π-bonded low-coordinated phosphorus cations, evaluating new types of bis-donor adducts.

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1999-01, Vol.144 (1), p.781-784
Hauptverfasser: Schoeller, W.W., Schneider, R., Tubbesing, U.
Format: Artikel
Sprache:eng
Schlagworte:
donor-acceptor formation
quantum chemical calculations
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Zusammenfassung:Mono-and bis-donor-acceptor formation (donor=AH 3 , Y = N, P, As, Sb, Bi and AH 2 , O, S, Se, Te) is discussed on the basis of quantum chemical (ab initio) calculations for π-bonded low-coordinated phosphorus cations, evaluating new types of bis-donor adducts.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509908546361