Kinetics and Mechanism of the Pudovik Reaction in the Series of Shiff Bases. Addition of Dialkylphosphites to Substituted N-Alkyl(Aryl)Benzylideneamines

Kinetics and Mechanism of the Pudovik Reaction in the Series of Shiff Bases. Addition of Dialkylphosphites to Substituted N-Alkyl(Aryl)Benzylideneamines

Kinetic and preparative investigation of the reaction of addition of dialkylphosphites to a serias of Shiff bases of the type Ar-CH˭N-R (R = Alk, Ar 3 ) (1) is investigated. On the basis of kinetic data obtained (Table) the nucleophilic addition mechanism is suggested.

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1999-01, Vol.147 (1), p.71-71
Hauptverfasser: Sobanov, A. A., Zolotukhin, A. V., Galkin, V. I., Galkina, I. V., Cherkasov, R. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:Kinetic and preparative investigation of the reaction of addition of dialkylphosphites to a serias of Shiff bases of the type Ar-CH˭N-R (R = Alk, Ar 3 ) (1) is investigated. On the basis of kinetic data obtained (Table) the nucleophilic addition mechanism is suggested.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509908053516