Structured Assembly of Heterometallic Arrays

Structured Assembly of Heterometallic Arrays

A range of heterometallic cage complexes can be prepared by step-wise metallation reactions of monolithiated primary amines and phosphines ([REHLi] n ; E= N, P) with various Group 13, 14 and 15 metal reagents. The p block imido and phosphinidine anions present in these species are novel ligand syste...

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1997-01, Vol.124 (1), p.103-112
Hauptverfasser: Beswick, Michael A., Davies, Maxwell K., Harmer, Christopher N., Hopkins, Alexander D., Mosquera, Marta E. G., Palmer, Julie S., Paver, Michael A., Raithby, Paul R., Wright, Dominic S.
Format: Artikel
Sprache:eng
Schlagworte:
Cages
heterometallic
ligands
main group
metallation
rings
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Beschreibung
Zusammenfassung:A range of heterometallic cage complexes can be prepared by step-wise metallation reactions of monolithiated primary amines and phosphines ([REHLi] n ; E= N, P) with various Group 13, 14 and 15 metal reagents. The p block imido and phosphinidine anions present in these species are novel ligand systems to main group and transition metals. This simple synthetic approach thereby provides a basis for structured assembly of a range of heterometallic cage and ring compounds.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509708545615