DESULFURISATION OF PHOSPHONYLATED THIOAMIDES: A NEW WAY TO FUNCTIONALISED AMINOPHOSPHONATES

DESULFURISATION OF PHOSPHONYLATED THIOAMIDES: A NEW WAY TO FUNCTIONALISED AMINOPHOSPHONATES

A new way to functionalised (aminomethyl)- or (aminoethyl)-phosphonates via the desulfurisation by nickel boride of phosphono substituted thioamides [(thiocarbamoyl)- and (thiocarbamoylmethyl)-hosphonates], readily available from phosphono-dithioesters and functionalised amines, is described.

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Bibliographische Detailangaben
Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1997-04, Vol.123 (1), p.247-254
Hauptverfasser: Roy-gourvennec, Sylve Le, Lemarie, Margareth, Masson, Serge
Format: Artikel
Sprache:eng
Schlagworte:
(N-phosphonomethyl)aminoacids
(Thiocarbamoyl)phosphonates
aminophosphonates
desulfurisation
N-(2-phosphonoethyl)aminoacids
nickel boride
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Beschreibung
Zusammenfassung:A new way to functionalised (aminomethyl)- or (aminoethyl)-phosphonates via the desulfurisation by nickel boride of phosphono substituted thioamides [(thiocarbamoyl)- and (thiocarbamoylmethyl)-hosphonates], readily available from phosphono-dithioesters and functionalised amines, is described.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509708044213