C-Spirooxyphosphoranyl (Pv) α-Anions. Alkylation and Olefination Chemistry

C-Spirooxyphosphoranyl (Pv) α-Anions. Alkylation and Olefination Chemistry

The chemical features of C-spirooxyphosphoranyl α-anions are investigated toward alkylation and olefination reactions. Proposed mechanistic pathways are based on low temperature 31 P-NMR data.

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Bibliographische Detailangaben
Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1996-04, Vol.111 (1-4), p.156-156
Hauptverfasser: Barkallah, Salim, Bojin, Mihaela L., Evans, Slayton A.
Format: Artikel
Sprache:eng
Schlagworte:
alkylation
olefination
Spirooxyphosphorane
α-phosphoranyl carbanion
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Beschreibung
Zusammenfassung:The chemical features of C-spirooxyphosphoranyl α-anions are investigated toward alkylation and olefination reactions. Proposed mechanistic pathways are based on low temperature 31 P-NMR data.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509608054785