SYNTHESIS OF ISOSTERIC ARSONOLIPIDS: RAC-3,4-DIACYLOXYBUTYLARSONIC ACIDS

SYNTHESIS OF ISOSTERIC ARSONOLIPIDS: RAC-3,4-DIACYLOXYBUTYLARSONIC ACIDS

Acylation of diphenyl rac-3,4-dihydroxybutyldithioarsonite with acyl chlorides and oxidation by hydrogen peroxide gave in low yields (7-14%) a new class of isosteric arsonolipids, rac-3,4-diacyloxybutylarsonic acids. The low yields are partially due to carbon-arsenic bond cleavage.

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Bibliographische Detailangaben
Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1995-09, Vol.106 (1-4), p.75-77
Hauptverfasser: Serves, Spyros V., Sotiropoulos, Demetrios N., Ioannou, Panayiotis V.
Format: Artikel
Sprache:eng
Schlagworte:
acylation
Arsonic acids
esters of alkyldithioarsonous acid
isosteric arsonolipids
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Beschreibung
Zusammenfassung:Acylation of diphenyl rac-3,4-dihydroxybutyldithioarsonite with acyl chlorides and oxidation by hydrogen peroxide gave in low yields (7-14%) a new class of isosteric arsonolipids, rac-3,4-diacyloxybutylarsonic acids. The low yields are partially due to carbon-arsenic bond cleavage.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509508027891