CORONAND-DERIVATE VON 1,6,6aλ4-TRITHIA-3,4-DIAZAPENTALENEN

CORONAND-DERIVATE VON 1,6,6aλ4-TRITHIA-3,4-DIAZAPENTALENEN

Aminolysis of 2,5-bis(aryloxy)-1,6,6aλ 4 -trithia-3,4-diazapentalenes 1 with coronand-amines yields step-wise 2-substituted and further 2,5-disubstituted derivatives 2-6, and with diamines bridged compounds 7. From 7 derivatives 8 and with diamines oligomers 9 and cryptands 10 are available. The X-r...

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1994-06, Vol.91 (1-4), p.81-91
Hauptverfasser: Lutze, G., Tittelbach, F., Graubaum, H., Ramm, M.
Format: Artikel
Sprache:eng
Schlagworte:
1,6,6aλ
coronands
cryptands
potassium complexes
Trithia-3,4-diazapentalenes
X-ray
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Zusammenfassung:Aminolysis of 2,5-bis(aryloxy)-1,6,6aλ 4 -trithia-3,4-diazapentalenes 1 with coronand-amines yields step-wise 2-substituted and further 2,5-disubstituted derivatives 2-6, and with diamines bridged compounds 7. From 7 derivatives 8 and with diamines oligomers 9 and cryptands 10 are available. The X-ray structure analysis of the complex 2b*KSCN is described.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509408021935