Selective Oxidation of Sulfides to Sulfoxides by Atmospheric Oxygen and Aldehyde Catalysed by NIII Complexes

Selective Oxidation of Sulfides to Sulfoxides by Atmospheric Oxygen and Aldehyde Catalysed by NIII Complexes

A new and efficient method for oxidising sulfides selectively to sulfoxides has been developed with atmospheric oxygen, in the presence of isobutyraldehyde and catalysed by Ni II complexes such as bis[1,3-bis-(p-methoxyphenyl)-1,3-propanedionato]nickel, [Ni(dmp) 2 ], and bis[acetylacetonato]nickel,...

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1994-07, Vol.92 (1-4), p.189-192
Hauptverfasser: Vincent, Stephane, Lion, Claude, Hedayatullah, Mir, Challier, Anthony, Delmas, Gerard, Magnaud, Gilbert
Format: Artikel
Sprache:eng
Schlagworte:
Ni complexes
oxidation
oxygen
Sulfides
sulfoxides
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Beschreibung
Zusammenfassung:A new and efficient method for oxidising sulfides selectively to sulfoxides has been developed with atmospheric oxygen, in the presence of isobutyraldehyde and catalysed by Ni II complexes such as bis[1,3-bis-(p-methoxyphenyl)-1,3-propanedionato]nickel, [Ni(dmp) 2 ], and bis[acetylacetonato]nickel, [Ni(acac) 2 ].
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509408021471